Awesome and Easy Science Experiments about N-Boc-2-pyrroline

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One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Formula: C9H15NO2, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 73286-71-2, Name is N-Boc-2-pyrroline, molecular formula is C9H15NO2

Asymmetric Hydroformylation and Hydrocarboxylation of Enamides. Synthesis of Alanine and Proline

Carbonyltris(triphenylphosphine)hydridorhodium (1) catalyzed the hydroformylation of N-vinylimides in the presence of optically active 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (DIOP) or 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(5H-dibenzophospholyl)butane (DIPHOL) to afford optically active alpha-amido aldehydes.Linear disubstituted N-vinylimides or -amides reacted very sluggishly, while the cyclic N-acyl-2-pyrroline (19) was very reactive.In the unsubstituted N-vinylimides moderate (20-40percent ee) asymmetric induction was observed.The optically active alpha-amido aldehydes were readily converted to the corresponding alpha-amino acids.Asymmetric hydrocarboxylation of the same substrates in the presence of bis(triphenylphosphine)palladium chloride (2) produced alpha-amido esters in low optical purity.

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Reference£º
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem