Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde1205-17-0, Name is 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde, SMILES is CC(CC1=CC2=C(OCO2)C=C1)C=O, belongs to pyrrolines compound. In a article, author is Zhukovsky, Daniil, introduce new discover of the category.
Synthetic Exploration of alpha-Diazo gamma-Butyrolactams
DIazo transfer reaction onto -butyrolactams (activated by -ethyloxalylation) gave rare -diazo -butyrolactams. Decomposition of the latter by Rh-2(OAc)(4) in the presence of alcohols and water gave products of O-H insertion of the respective metal-cabene species. Silver triflate (1 mol-%) was found to convert the -butyrolactams investigated into 1,5-dihydro-2H-pyrrol-2-ones which represent versatile building blocks. Particular instability was noted for -diazo -butyrolactams bearing alkyl or o-substituted aryl substituents on the nitrogen atom. These were found to dimerize in solution or upon storage at room temperature to give fully conjugated bis-hydrazones along with the loss of a nitrogen molecule.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 1205-17-0. Name: 2-Methyl-3-(3,4-methylenedioxyphenyl)propionaldehyde.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem