Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is HOPMAN, JCP, once mentioned the application of 155899-66-4, Name is (3aR,4S,6R,6aS)-6-Amino-2,2-dimethyltetrahydro-3aH-cyclopenta[d][1,3]dioxol-4-ol, molecular formula is C8H15NO3, molecular weight is 173.2096, MDL number is MFCD20527303, category is pyrrolines. Now introduce a scientific discovery about this category, Application In Synthesis of (3aR,4S,6R,6aS)-6-Amino-2,2-dimethyltetrahydro-3aH-cyclopenta[d][1,3]dioxol-4-ol.
CHIRALITY PRESERVATION IN PYRROLINONE IRON TETRACARBONYL COMPLEXES – A ROUTE TO ENANTIOPURE 5-SUBSTITUTED PYRROLINONES
The enantiopure iron complex 4 reacts under the influence of BF3 . OEt(2) with allylsilanes and enol acetates through a cationic intermediate in which the chirality of 4 is preserved, yielding enantiopure 5-substituted 3-pyrrolin-2-ones.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem