Chemical Research Letters, May 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world., SDS of cas: 110351-94-5, Introducing a new discovery about 110351-94-5, Name is (S)-4-Ethyl-4-hydroxy-7,8-dihydro-1H-pyrano[3,4-f]indolizine-3,6,10(4H)-trione, molecular formula is C13H13NO5, belongs to pyrrolines compound. In a document, author is Sattler, Lars E..
Iodonium Cation-Pool Electrolysis for the Three-Component Synthesis of 1,3-Oxazoles
The synthesis of 1,3-oxazoles from symmetrical and unsymmetrical alkynes was realized by an iodonium cation-pool electrolysis of I-2 in acetonitrile with a well-defined water content. Mechanistic investigations suggest that the alkyne reacts with the acetonitrile-stabilized I+ ions, followed by a Ritter-type reaction of the solvent to a nitrilium ion, which is then attacked by water. The ring closure to the 1,3-oxazoles released molecular iodine, which was visible by the naked eye. Also, some unsymmetrical internal alkynes were tested and a regioselective formation of a single isomer was determined by two-dimensional NMR experiments.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. 110351-94-5, you can contact me at any time and look forward to more communication. SDS of cas: 110351-94-5.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem