New discoveries in chemical research and development in 2021.In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. In an article, author is Hirai, Sho, once mentioned the application of 17924-92-4, Name is (S,E)-14,16-Dihydroxy-3-methyl-3,4,5,6,9,10-hexahydro-1H-benzo[c][1]oxacyclotetradecine-1,7(8H)-dione, molecular formula is C18H22O5, molecular weight is 318.3643, MDL number is MFCD00133085, category is pyrrolines. Now introduce a scientific discovery about this category, Formula: https://www.ambeed.com/products/17924-92-4.html.
Acid promoted dimerization of beta-amino-alpha,beta-unsaturated amides affording bis(functionalized) pyrrolinones
Polysubstituted pyrrolinones were synthesized by the dimerization of 3-amino-2-butenamides via treatment with 0.5 equiv p-TsOH under mild reaction conditions, including oxidation and 1,2-migration of the methyl group. This method is practically advantageous compared to the conventional methods for the preparation of pyrrolinones, because it does not require difficult experimental manipulations and special reagents such as metal catalysts and oxidants. Because the structures of beta-amino-alpha,beta-unsaturated amides can be easily modified by changing the precursors, beta-keto amide and amine, synthesis of diverse pyrrolinones is possible. (C) 2016 Elsevier Ltd. All rights reserved.
The potential utility of systematic synthetic strategy will be applicable to efficient generations of chemical libraries of compounds to find ‘hit’ molecules. In my other articles, you can also check out more blogs about 17924-92-4. Formula: https://www.ambeed.com/products/17924-92-4.html.
Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem