Chemical Research Letters, May 2021. The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 256-96-2, Name is 5H-Dibenzo[b,f]azepine, SMILES is C12=CC=CC=C1C=CC3=CC=CC=C3N2, in an article , author is de Koning, H, once mentioned of 256-96-2, Computed Properties of https://www.ambeed.com/products/256-96-2.html.
New applications of N-acyliminium precursors: Tetracarbonyliron-mediated stereoselective alkylations of 5-(R)-isopropoxy-3-pyrrolin-2-ones
Lewis acid catalyzed allylic substitutions with several nucleophiles at C-5 of the cis-tetracarbonyliron complexes of N-acetyl- and N-tosyl-5-(R) -isopropoxy-3-pyrrolin-2-ones occur highly regio- and stereoselectively. The results are interpreted as being indicative of the intermediacy of a ( pi-allyl)tetracarbonyliron cation, with possible preceding formation of an N-acyl- or an N-tosyliminium ion.
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Reference:
Pyrroline – Wikipedia,
,1-Pyrroline | C4H7N – PubChem