Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 58081-05-3, is researched, SMILESS is O=C1OC[C@H](O)C1, Molecular C4H6O3Journal, Tetrahedron called Enantiomerically pure β,γ-epoxyesters from β-hydroxylactones: synthesis of β-hydroxyesters and (-)-GABOB, Author is Larcheveque, M.; Henrot, S., the main research direction is hydroxybutanolide ring cleavage iodotrimethylsilane; iodohydrin cyclization silver oxide; epoxy ester preparation alkylation cuprate; hydroxy ester.Synthetic Route of C4H6O3.
The preparation of enantiomerically pure β,γ-epoxy esters was achieved by chemoselective opening of β-hydroxybutanolides with Me3SiI followed by cyclization of the resulting iodohydrins with Ag2O. The reaction of these epoxy esters with lithio- or magnesiocuprates afforded stereochemically pure α-substituted-β-hydroxy esters. Alternatively, the title compound, (R)-H2NCH2CH(OH)CH2CO2H, was synthesized in optically pure form from the iodohydrin (R)-ICH2CH(OH)CH2CO2Et.
There are many compounds similar to this compound(58081-05-3)Synthetic Route of C4H6O3. if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.
Reference:
Pyrroline – Wikipedia,
1-Pyrroline | C4H7N – PubChem